Barium oxalate

Barium oxalate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.007.471
UNII
  • InChI=1S/C2H2O4.Ba/c3-1(4)2(5)6;/h(H,3,4)(H,5,6);/q;+2/p-2 checkY
    Key: GXUARMXARIJAFV-UHFFFAOYSA-L checkY
  • InChI=1/C2H2O4.Ba/c3-1(4)2(5)6;/h(H,3,4)(H,5,6);/q;+2/p-2
    Key: GXUARMXARIJAFV-NUQVWONBAK
  • [Ba+2].[O-]C(=O)C([O-])=O
Properties[1]
BaC2O4
Molar mass 225.345 g·mol−1
Appearance White powder
Odor Odorless
Density 2.658 g/cm3
Melting point 400 °C (752 °F; 673 K) (decomposes)
0.0075 g/100g
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkYX markN ?)
Infobox references

Barium oxalate is a chemical compound with the chemical formula BaC2O4. It is a barium salt of oxalic acid. It consists of barium cations Ba2+ and oxalate anions C2O2−4. It is a white odorless powder that has rarely been used as a colorant in magnesium-containing pyrotechnic formulas.

Properties

It is extremely insoluble in water and converts to barium oxide when heated.

Preparation

The raw materials that are required to prepare barium oxalate are oxalic acid and barium hydroxide (or its octahydrate).

It can be prepared by using an oxalic acid solution and a barium chloride solution, with the reaction as follows:

BaCl2 + H2C2O4 → BaC2O4 + 2 HCl

Safety

Though largely stable, barium oxalate can be reactive with strong acids. A mild skin irritant, the compound is considered toxic when ingested, causing nausea, vomiting, kidney failure, and injury to the gastrointestinal tract.

References

  1. ↑ Haynes, William M., ed. (2016). CRC Handbook of Chemistry and Physics (97th ed.). Boca Raton, Florida: CRC Press. p. 4–50. ISBN 9781498754293.
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