Barium oxalate
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| Identifiers | |
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3D model (JSmol) |
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| ChemSpider | |
| ECHA InfoCard | 100.007.471 |
PubChem CID |
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CompTox Dashboard (EPA) |
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| Properties[1] | |
| BaC2O4 | |
| Molar mass | 225.345 g·mol−1 |
| Appearance | White powder |
| Odor | Odorless |
| Density | 2.658 g/cm3 |
| Melting point | 400 °C (752 °F; 673 K) (decomposes) |
| 0.0075 g/100g | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references | |
Barium oxalate is a chemical compound with the chemical formula BaC2O4. It is a barium salt of oxalic acid. It consists of barium cations Ba2+ and oxalate anions C2O2−4. It is a white odorless powder that has rarely been used as a colorant in magnesium-containing pyrotechnic formulas.
Properties
It is extremely insoluble in water and converts to barium oxide when heated.
Preparation
The raw materials that are required to prepare barium oxalate are oxalic acid and barium hydroxide (or its octahydrate).
It can be prepared by using an oxalic acid solution and a barium chloride solution, with the reaction as follows:
- BaCl2 + H2C2O4 → BaC2O4 + 2 HCl
Safety
Though largely stable, barium oxalate can be reactive with strong acids. A mild skin irritant, the compound is considered toxic when ingested, causing nausea, vomiting, kidney failure, and injury to the gastrointestinal tract.
References
- ↑ Haynes, William M., ed. (2016). CRC Handbook of Chemistry and Physics (97th ed.). Boca Raton, Florida: CRC Press. p. 4–50. ISBN 9781498754293.
External links
Media related to Barium oxalate at Wikimedia Commons- rec.pyrotechnics FAQ
