Monoterpenol O-acetyltransferase

Monoterpenol O-acetyltransferase
Identifiers
EC no.2.3.1.69
CAS no.78990-59-7
Databases
BRENDAenzyme data
ExPASyNiceZyme view
KEGGenzyme entry
MetaCycmetabolic pathway
Rheareactions
PDB structuresRCSB PDB PDBe PDBsum
Gene OntologyAmiGO / QuickGO
Search
PMCarticles
PubMedarticles
NCBIproteins

Monoterpenol O-acetyltransferase (EC 2.3.1.69) is an enzyme that catalyzes the general chemical reaction

a monoterpenol +acetyl-CoA a monoterpenol acetate ester + CoA

Menthol is a typical substrate of the enzyme characterised from peppermint and is converted to menthyl acetate:[1][2]

+
 
 
 
 
Rightward reaction arrow
 
 
 
 

This enzyme belongs to the family of transferases, specifically those acyltransferases transferring groups other than aminoacyl groups. The systematic name of this enzyme class is acetyl-CoA:monoterpenol O-acetyltransferase. This enzyme is also called menthol transacetylase.[3]

References

  1. ↑ Croteau R, Hooper CL (May 1978). "Metabolism of Monoterpenes: Acetylation of (−)-Menthol by a Soluble Enzyme Preparation from Peppermint (Mentha piperita) Leaves". Plant Physiology. 61 (5): 737–42. doi:10.1104/pp.61.5.737. PMC 1091967. PMID 16660375.
  2. ↑ Martinkus C, Croteau R (July 1981). "Metabolism of monoterpenes - evidence for compartmentation of L-menthone metabolism in peppermint (Mentha piperita) leaves". Plant Physiology. 68 (1): 99–106. doi:10.1104/pp.68.1.99. PMC 425897. PMID 16661898.
  3. ↑ Enzyme 2.3.1.69 at KEGG Pathway Database.