Californium(III) oxychloride

Californium oxychloride
Names
IUPAC name
Californium oxychloride
Identifiers
3D model (JSmol)
  • InChI=1S/Cf.ClH.O/h;1H;/q+3;;-2/p-1
    Key: XKTKIHYWYXTIDP-UHFFFAOYSA-M
  • [Cf+3].[Cl-].[O-2]
Properties
CfClO
Molar mass 302 g·mol−1
Appearance pale green crystals[1]
Related compounds
Related compounds
Einsteinium oxychloride
Berkelium oxychloride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Californium oxychloride (CfOCl) is a radioactive salt first discovered in measurable quantities in 1960. It was the first californium compound ever isolated.[2]

Synthesis

Treatment of Cf2O3 with moist hydrogen chloride or CfCl3 with water vapor.[3]

Crystal structure

Californium oxychloride exhibits a PbFCl-type crystal structure. Its lattice parameters are a = 3·956±0.002 Å and c = 6·662±0·009 Å.[4]

See also

References

  1. ↑ Fundamental Nuclear Energy Research. Atomic Energy Commission. 1968. p. 274. Retrieved 16 July 2023.
  2. ↑ Seaborg, Glenn T. (1963). Man-Made Transuranium Elements. Prentice-Hall.
  3. ↑ Seaborg, G. T.; Katz, Joseph J.; Morss, L. R. (6 December 2012). The Chemistry of the Actinide Elements: Volume 2. Springer Science & Business Media. p. 1046. ISBN 978-94-009-3155-8. Retrieved 16 July 2023.
  4. ↑ Copeland, J.C.; Cunningham, B.B. (1969). "Crystallography of the compounds of californium—II crystal structure and lattice parameters of californium oxychloride and californium sesquioxide". Journal of Inorganic and Nuclear Chemistry. 31 (3): 733–740. doi:10.1016/0022-1902(69)80020-5.